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Sidhik, Siraj; Metcalf, Isaac; Li, Wenbin; Kodalle, Tim; Dolan, Connor J; Khalili, Mohammad; Hou, Jin; Mandani, Faiz; Torma, Andrew; Zhang, Hao; et al (, Science)We present a design strategy for fabricating ultrastable phase-pure films of formamidinium lead iodide (FAPbI3) by lattice templating using specific two-dimensional (2D) perovskites with FA as the cage cation. When a pure FAPbI3precursor solution is brought in contact with the 2D perovskite, the black phase forms preferentially at 100°C, much lower than the standard FAPbI3annealing temperature of 150°C. X-ray diffraction and optical spectroscopy suggest that the resulting FAPbI3film compresses slightly to acquire the (011) interplanar distances of the 2D perovskite seed. The 2D-templated bulk FAPbI3films exhibited an efficiency of 24.1% in a p-i-n architecture with 0.5–square centimeter active area and an exceptional durability, retaining 97% of their initial efficiency after 1000 hours under 85°C and maximum power point tracking.more » « less
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